Through burning biomass pellets, whether they are made from wood, straw, grass or any other form of biomass they produce ash. The percentage of ash and possibly a clinker is specific to that raw material.
Straw Pellets
Wheat, Barley and other types of straw pellets are becoming more popular as fuel pellets. With regards to pellet production at harvest the material is at the correct moisture content for pellet production. This means drying equipment is not required, and this therefore reduces capital expenditure on equipment, and the cost of production. Productivity for straw pellets is also a lot higher than wood pellets, as straw is not as dense as wood, and is more malleable. However straw does have a disadvantage, as it does not have as much lignin as wood. Since lignin is what gives a pellet its strength, straw pellets have less mechanical strength than wood pellets. This means straw pellets tend to produce more fines than wood pellets, and with regards to combustion this causes more sintering and clinkers to form. The reduced percentage of lignin and increased percentage of fines is not the only reason straw pellets produce more ash and clinker. Straw ash has a lower melting point than wood ash, and ash melting is what forms a clinker.
So straw pellets have advantages with regards to higher pellet production, and have a similar heat value to wood pellets. However during combustion they do produce more ash and clinker so can only be burned in a suitable pellet boiler. The final point is straw generally contains a high percentage of chlorine, and chlorine or chloride is a high temperature corrosive. With regards to a suitable boiler to withstand this corrosion, some manufactures have focused on stainless steel. Stainless steel does have good corrosion resistance, however is susceptible to cracking and stainless steel boilers as very expensive. The best advice is just keep it simple, look for a boiler similar to the old coal boilers, these are built like a tank and resist corrosion though the fact of been very thick.
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